期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 132, 期 48, 页码 17108-17110出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja108949w
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资金
- NCRR NIH HHS [S10 RR016640-01] Funding Source: Medline
- NIGMS NIH HHS [R01 GM035249, GM035249, R01 GM035249-25] Funding Source: Medline
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0848460] Funding Source: National Science Foundation
The stereospecific cross-coupling of enantioenriched nonbenzylic secondary alkyl boron compounds has been achieved. The high selectivity toward product formation over an undesired beta-H elimination pathway is achieved via an intramolecular coordination of an ancillary carbonyl to the metal center in the diorganopalladium intermediate.
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