期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 132, 期 19, 页码 6660-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja101456c
关键词
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资金
- J. Evans Attwell-Welch Postdoctoral Fellowship
- Robert A. Welch Foundation [C-1680]
- Rice University
The combination of peptide molecular recognition and residue-selective dirhodium catalysis allows modification of aromatic side chains that is selective for coil structures. A rate enhancement of >10(3) relative to nonselective dirhodium modification was observed. The increased reactivity of this approach creates the first selective chemical modification of the phenylalanine residue.
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