期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 132, 期 46, 页码 16343-16345出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja107288x
关键词
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资金
- Packard Foundation
- National Science Foundation
- Deutsche Forschungsgemeinschaft, U.S.
- Deutsche Forschungsgemeinschaft, German
A series of planar aryl-substituted bis(imino)pyridine cobalt azide complexes were prepared and evaluated as synthetic precursors for the corresponding cobalt nitrido compounds. Thermolysis or photolysis of two examples resulted in intramolecular C-H activation of the benzylic positions of the aryl substituents. For the mesityl-substituted compound, C-H activation by the putative nitride resulted in formation of a neutral imine ligand and modification of the chelate by hydrogen transfer to the imine carbon.
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