期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 132, 期 33, 页码 11434-11436出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja1048658
关键词
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资金
- Dutch Ministry of Economic Affairs [TMM 6976]
The creation of cyclodextrin patterns on a fluorescent reporter surface by microcontact printing provides a versatile orthogonal surface modification method. The alkyne-beta-cyclodextrin surface is prepared through a click reaction on alkyne-terminated coumarin monolayers. The resulting alkyne-beta-cyclodextrin surface can be functionalized through supramolecular microcontact printing on cyclodextrin host patterns and by reactive microcontact printing-induced click chemistry on the alkyne-terminated patterns. The orthogonal covalent and supramolecular host-guest functionalization of the surface, and its specificity as well as selectivity, is demonstrated by sequential and one-step printing procedures.
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