4.8 Article

Fe-g-C3N4-Catalyzed Oxidation of Benzene to Phenol Using Hydrogen Peroxide and Visible Light

期刊

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 131, 期 33, 页码 11658-+

出版社

AMER CHEMICAL SOC
DOI: 10.1021/ja903923s

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资金

  1. NSFC [20537010, 20603007]
  2. NCET [07-0192]
  3. 973 Program [2007CB613306]
  4. AvH Foundation
  5. ENERCHEM

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A bioinspired iron-based catalyst with semiconductor photocatalytic functions in combination with a high surface area holds promise for synthetic chemistry via combining photocatalysis with organosynthesis. Here exemplified for phenol synthesis, Fe-g-C3N4/SBA-15 is able to oxidize benzene to phenol with H2O2 even without the aid of strong acids or alkaline promoters. By taking advantage of both catalysis and photocatalyisis functions of g-C3N4 nanoparticles, the yield of the phenol. can be markedly promoted.

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