期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 131, 期 14, 页码 5072-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja900327e
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资金
- Scripps Research Institute
- National Institutes of Health [NIGMS, 1 R01 GM084019-01A1]
- Amgen and Lilly
- A. P. Sloan Foundation
Pd(II)-catalyzed meta-olefination of highly electron-deficient arenes is achieved through the use of a rationally designed mutually repulsive ligand. The combination of directed and nondirected C-H functionalization of arenes provides a versatile route for the synthesis of highly sought after 1,2,4-trisubstituted arenes.
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