期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 131, 期 6, 页码 2078-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja809088v
关键词
-
资金
- Office of Science, Office of Basic Energy Sciences
- U.S. Department of Energy [DE-AC02-05 CH11231]
The atypical 1:2 complexation between an etectron-rich crown ether host and electron-deficient naphthalene diimide-based guests led to the formation of alternative donor-acceptor (ADA) stacks. The ADA stacks can be expediently obtained in high yield as polycrystalline aggregates from solution. More remarkably, the high degree of organization has also been realized in a simple solid-to-solid mechanical grinding process. The solid-state structures have been verified by solid-state NMR spectroscopy, single crystal, and powder X-ray diffraction analysis. The current findings not only provide convenient ways of obtaining novel donor-acceptor stacks involving a macrocyclic host but also represent an important step in transferring electroactive host-guest systems from solution to the solid state.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据