期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 131, 期 22, 页码 7494-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja900805y
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资金
- Ministry of Education, Culture, Sports, Science, and Technology, Japan
- Novartis Foundation (Japan)
- Takeda Pharmaceutical Company Award in Synthetic Organic Chemistry, Japan
An intermolecular nickel-catalyzed addition reaction in which isatoic anhydrides react with alkynes to afford substituted quinolones has been developed. A mechanistic rationale is proposed, implying oxidative addition of Ni(0) to a carbamate, which allows intermolecular addition to alkynes via decarboxylation.
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