期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 131, 期 32, 页码 11274-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja902808q
关键词
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资金
- Netherlands Organization for Scientific Research (NWO)
- STW/Nanoned
A prototype surfactant system was developed-with the unique feature that it can be switched between an aggregated, amphiphilic state and a nonaggregated, nonamphiphilic state using external stimuli. This switchable surfactant system uses the reversible formation of a dynamic covalent bond for pH- and temperature-triggered on/off seff-assembly of micellar aggregates by reversible displacement of the equilibrium between nonamphiphilic building blocks and their amphiphilic counterparts. The potential for application in controlled-release systems is shown by reversible uptake and release of an organic dye in aqueous media.
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