期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 131, 期 18, 页码 6368-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja901731z
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资金
- U.S. Department of Energy [DE-FC36-07GO17033]
- National Science Foundation [CHE-0449634]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0910761] Funding Source: National Science Foundation
The construction of a metal-organic framework (MOF) with a pcu-a topology using a preassembled soluble molecular octahedron has been realized experimentally. The resulting MOF can also be reversibly converted to the molecular octahedron. All such conversions are based on axial-ligand substitution reactions on the molecular octahedron.
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