期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 131, 期 25, 页码 8775-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja901587t
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资金
- Environment and Natural Resources of the Walloon Region (Belgium)
- CNRS
- ANR [ANR06-CO2-008]
Hydrogen sulfide gravimetric isotherm adsorption measurements were carried out on MIL-53(Al, Cr, Fe), MIL-47(V), MIL-100(Cr), and MIL-101(Cr) metal-organic frameworks (MOFs). A two-step adsorption mechanism related to a breathing effect was observed for MIL-53 terephthalate-based MOFs. Methane adsorption measurements highlighted the regenerability of MIL-53(Al, Cr) and MIL-47(V) MOFs after H2S treatment, whereas MIL-100 and MIL-101 CH4 adsorption capacities were significantly decreased.
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