期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 131, 期 1, 页码 6-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja8043147
关键词
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资金
- Grant-in-Aid for Scientific Research [17105005, 19350069]
- Ministry of Education, Culture, Sports, Science and Technology (MEXT) of Japanese Government
- Grants-in-Aid for Scientific Research [19350069] Funding Source: KAKEN
In this study, we have photochemically fabricated a gold cluster (Au-n), composed of several tens of atoms, in a polymer matrix and concurrently investigated the photoreactivity of newly formed clusters at the single-cluster level. Our attempt enabled the in situ observation of individual ligand-free Au-n clusters with a resolution of the number of atoms. In addition, the procedure revealed the photoinduced reaction of excited Au-n clusters with O-2 for the first time.
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