4.8 Article

Effect of TMEDA on Iron-Catalyzed Coupling Reactions of ArMgX with Alkyl Halides

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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 131, 期 17, 页码 6078-+

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AMER CHEMICAL SOC
DOI: 10.1021/ja901262g

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  1. Ministry of Education, Culture, Sports, Science and Technology Japan [18064014]
  2. Grants-in-Aid for Scientific Research [18064014] Funding Source: KAKEN

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A new reaction mechanism for the iron-catalyzed cross-coupling reaction of ArMgX with alkyl halides using (TMEDA)FeAr2 and (TMEDA)Fe(Ar)Br is proposed on the basis of the isolation and reaction of these organoiron intermediates.

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