期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 131, 期 7, 页码 2434-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja809078d
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资金
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0847258] Funding Source: National Science Foundation
The reaction of a sulfamate ester derived rhodium nitrenoid species with an alkyne produces a versatile intermediate, capable of cascading into a wide variety of secondary transformations. The nature of the intermediate has been probed by reactivity studies, and the synthetic utility of the cascade process, which facilitates the construction of complex heterocyclic structures from remarkably simple acyclic precursors, is highlighted.
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