4.8 Article

Polymerization of Enantiopure Monomers Using Syndiospecific Catalysts: A New Approach To Sequence Control in Polymer Synthesis

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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 131, 期 44, 页码 16042-+

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AMER CHEMICAL SOC
DOI: 10.1021/ja9075327

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资金

  1. Department of Energy [DE-FG02-05ER15687]
  2. National Science Foundation [CHE-0809778]
  3. ENSCP
  4. CNRS
  5. U.S. Department of Energy (DOE) [DE-FG02-05ER15687] Funding Source: U.S. Department of Energy (DOE)

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The ring-opening polymerization of a mixture of enantiomerically pure but different monomers using an yttrium complex as initiator proceeds readily at room temperature to give the corresponding highly alternating polyester.

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