期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 131, 期 44, 页码 16027-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja906302t
关键词
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资金
- NSF [DMR-0846958, CHEM-0809335]
- Division Of Materials Research
- Direct For Mathematical & Physical Scien [0846958] Funding Source: National Science Foundation
Under diverse and dramatically different chemical environments, including organic solvents, an ionic-Liquid, and a deep eutectic solvent, a series of porous anionic framework materials that contain size-tunable, ion-exchangeable extraframework organic cations have been prepared. Even though a large fraction of the pore space is occupied with charge-balancing cations, some of these materials exhibit a very high gas uptake capacity (e.g., 70.6 cm(3)/g for CO2 at 1 atm and 273 K), suggesting that the charged anionic framework and extraframework cations may help to enhance the gas adsorption.
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