期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 131, 期 19, 页码 6676-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja9025193
关键词
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资金
- National Institutes of Health [GM 58160, GM 1S10RR13886-01]
- Spanish MEC
- German Academic Exchange Service
An intramolecular enantioselective metal-catalyzed dearomatization reaction is described. This procedure allows the dearomatization of naphthalene derivatives through an electrophilic aromatic substitution-type reaction on a Pd(II) intermediate. The high yields and enantioselectivities achieved make this procedure a valuable method for synthetic chemists.
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