期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 131, 期 34, 页码 12415-12419出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja904782h
关键词
-
资金
- NSF [CHE 0718281]
- Office of Energy Efficiency and Renewable Energy through the Hydrogen Sorption Center of Excellence
Six prototype microporous metal-organic frameworks (MOFs) HKUST-1, MOF-505, MOF-508, MIL-53, MOF-5, and ZIF-8 with variable structures, porosities were examined for their acetylene storage, highlighting HKUST-1 as the highest acetylene storage material ever reported with an uptake of 201 cm(3)/g at 295 K and 1 atm. To locate the acetylene binding sites within HKUST-1, neutron powder diffraction studies on acetylene loaded HKUST-1 were carried out and have conclusively established the significant contribution of open Cu2+ sites for acetylene storage by their strong preferred interactions with acetylene molecules. The binding properties of acetylene gas at different sites were further investigated by first-principles calculations.
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