期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 131, 期 2, 页码 729-733出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja807167y
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资金
- NIH [GM 59932]
- China scholarship council
A general protocol for the rhodium-catalyzed oxidative carbonylation of arenes to form esters has been developed, A broad substrate scope has been demonstrated allowing carbonylation of electron-rich, electron-poor, and heterocyclic arenes, and the reaction shows wide functional group tolerance and excellent regioselectivities. Up to 96% yield of ortho-substituted aryl or heteroaryl carboxylic esters were obtained with this methodology. The possible mechanism for the rhodium-catalyzed oxidative carbonylation reaction was proposed in this article. Studies show that Oxone play an important role in the transformation.
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