期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 131, 期 8, 页码 2792-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja8097492
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资金
- Ministry of Education, Culture, Sports, Science and Technology, Japan
- The Science Research Promotion Fund
Ruthenium-catalyzed regioselective direct amino- and alkoxycarbonylations of aromatic rings via C-H bond cleavage using chlorocarbonyl compounds are described. A broad generality of amide and ester groups was achieved taking advantage of the wide availability of carbonylating agents. Alkyl chloroformates, inapplicable to usual Friedel-Crafts methods, can also be used for direct catalytic alkoxycarbonylation.
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