期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 131, 期 35, 页码 12516-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja900893p
关键词
-
Postsynthetic modification of a porous MOF, Zn4O(trans-4,4'-stilbene dicarboxylate)(3),with Br-2 results in bromination of the stilbene units. This is a heterogeneous process, with the stereocontrol originating in the rigidity of the coordinated ligand and the porous nature of the MOF, which allows solution-like access to reactive sites. X-ray diffraction and N-2 sorption studies suggest that partial bromination serves to increase the stability of this interpenetrated MOF structure.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据