期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 131, 期 14, 页码 5032-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja809917g
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资金
- NSERC of Canada
- Canadian Foundation for Innovation
- HSM Systems Inc.
- U.S. Department of Energy
LiH and Ti-doped At react quantitatively with H-2 in Me2O solution to form LiAlH4 under mild conditions. The solvent is easily vented along with excess H-2 on completion, leaving dry Ti-doped LiAlH4; this releases similar to 7 wt % H-2 commencing at 80 degrees C with excellent kinetics.
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