4.8 Article

Metal-Free Oxidative Cross-Coupling of Unfunctionalized Aromatic Compounds

期刊

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 131, 期 5, 页码 1668-+

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AMER CHEMICAL SOC
DOI: 10.1021/ja808940n

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资金

  1. Ministry of Education Culture, Sports, Science, and Technology, Japan
  2. New Energy and Industrial Technology Development Organization (NEDO) of Japan
  3. JSPS for Young Scientists
  4. Grants-in-Aid for Scientific Research [21249002] Funding Source: KAKEN

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A new strategy for mixed biaryl synthesis has been developed using the hypervalent iodine(III) reagents. The unique reactivities of the sigma-heteroaryl iodine(III) intermediates generated in situ are the key element for the unusual metal catalyst-free transformations and strict control of the product selectivities.

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