期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 131, 期 2, 页码 662-670出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja806962e
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资金
- U.S. National Science Foundation [CHE-0456892, 0809179]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0809179] Funding Source: National Science Foundation
O-Alkyl synthetic analogues of the green fluorescent protein chromophore are nonfluorescent in solution but demonstrate a bright emission in the crystalline state. Three-dimensional steady-state and time-resolved emission spectroscopies in the solid state, as well as single-crystal X-ray diffraction, reveal the nature of complex emission in the crystals. A hypsochromic emission shift with an increase of the alkyl size is determined by the monomer-aggregate emission ratio.
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