期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 131, 期 46, 页码 16634-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja906695h
关键词
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资金
- Natural Science Foundation of China [20771091, 20721001, 90922011]
- 973 Program [2007CB815301]
- Ministry of Education [NCET-06-0563]
Intense solution and solid state phosphorescence was observed on a novel photostable gold (I)-sitver(I) cluster with hypercoordinated carbon, [Au6Ag2(C)(dppy)(6)](BF4)(4), which has a core structure of a hexagold(I) octahedron with two silver(I) atoms capping on a pair of its faces; the incorporation of silver atoms enhances the rigidity and integrity of the cluster.
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