期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 131, 期 11, 页码 3850-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja9002603
关键词
-
资金
- NSF [CHE-042565]
- Wyeth Pharmaceuticals
The first Rh(I)-catalyzed addition of alkenylboron reagents to imines is described. The Rh(I)-catalyzed addition of potassium alkenyltrifluoroborate salts to both aromatic and aliphatic N-tert-butanesulfinyl aldimines proceeds in good yields (up to 97%) and with very high diastereoselectivities (95:5 to >99:1). This new method enables the general and efficient asymmetric synthesis of the important class of alpha-branched allylic amines from readily available and stable starting materials.
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