期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 131, 期 1, 页码 42-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja808331g
关键词
-
资金
- NSFC [BK2008029]
- 973 Project [2009CB623200]
Metal.-organic coordination (MOC)-type ferroelectrics, cobalt(II) (R)-2-methylpiperazine (MPPA) trichloride [(COCl3)-Cl-II(H-MPPA)], was constructed through hydrogen bonds. It is a good ferroelectric candidate with a P-s = 6.8 mu C center dot cm(-2) as high as almost twice that of triglycine sulfate (P-s = 3.5 mu C center dot cm(-2)) and significantly larger than that of KH2PO4 at the low-temperature ferroetectric phase Fdd2. [(COCl3)-Cl-II(H-MPPA)] is the first example of ferroelectric MOC that can really reach the spontaneous polarization status and opens up a new avenue to explore novel MOC-based ferroelectrics.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据