Cylindrical Superparticles from Semiconductor Nanorods

In this communication, we report a synthesis of anisotropic colloidal superparticles (SPs) from CdSe/CdS semiconductor nanorods. These anisotropic SPs are cylindrical disks or stacked-disk arrays. We attribute the major driving forces controlling the SP shape to interparticle interactions between nanorods and solvophobic interactions between a superparticle and its surrounding solvent. According to their sizes (or volumes), the SPs adopt either single- or multilayered structures. In addition, these SIPS exhibit linearly polarized emissions, demonstrating their potential role as useful components in devices such as polarized light-emitting diodes and electrooptical modulators.