期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 131, 期 36, 页码 12989-12993出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja902629y
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资金
- Natural Sciences and Engineering Research Council of Canada [STPGP 350501-07]
- W. M. Keck Foundation
- Army Research Office
On the basis of high resolution STM images and DFT modeling, we have resolved low- and high-coverage structures of methylthiolate (CH3S) self-assembled on the Au(111) surface. The key new finding is that the building block of all these structures has the same stoichiometry of two thiolate species joined by a gold adatom. The self-arrangement of the methylthiolate-adatom complexes on the surface depends critically on their stereochemical properties. Variations of the latter can produce local ordering of adatom complexes with either (3 x 4) or (3 x 4 root 3) periodicity. A possible structural connection between the (3 x 4 root 3) structure and commonly observed (root 3 x root 3)R30 degrees phase in methylthiolate self-assembled monolayers is developed by taking into account the reduction in the long-range order and stereochemical isomerization at high coverage. We also suggest how the observed self-arrangements of methylthiolate may be related to the c(4 x 2) phase of its longer homologues.
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