期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 131, 期 22, 页码 7528-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja901799s
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资金
- National Science Foundation [CHE-0450638]
- Swedish Research Council
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0848280] Funding Source: National Science Foundation
An efficient cyclocarboamination reaction of nonactivated alkynes with aziridines, catalyzed by Lewis or Bronsted acids, to form 2,3-dihydropyrroles through a format [3+2] cycloaddition, is described. The reaction provides a wide range of polysubstituted dihydropyrroles in a highly regioselective manner, is scalable, proceeds under mild reaction conditions, and uses low catalyst loadings.
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