期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 131, 期 12, 页码 4184-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja809985t
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资金
- U.S. Department of Energy through the National Energy Technology Laboratory [DEFG26-04NT42121]
New levels of surface area are achieved in a coordination polymer (UMCM-2, University of Michigan Crystalline Material) derived from zinc-mediated coordination copolymerization of a dicarboxylic and tricarboxylic acid. In addition to a large micropore contribution to the surface area, mesopores are also present. In contrast to the recently reported coordination copolymer UMCM-1, which has a mesoporous channel, UMCM-2 is built from three types of cages. In spite of exceptional porosity, both of these coordination polymers are thermally robust. Hydrogen uptake performance of UMCM-2 approaches 7 wt% at 77 K.
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