期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 131, 期 9, 页码 3392-3395出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja809831a
关键词
-
资金
- National Science Foundation
- Japan Society Tor the Promotion of Science
We studied At, Kr, CO, and N-2 going into and out of a chemically opened fullerene, 1. We measured the equilibrium constant, K-eq, for the formation of X@1. K-eq is particularly large for Ar, probably due to the large van der Waals attraction between the Ar atom and the fullerene cage. We measured rate constants and activation energies for the unimolecular reaction X@1 -> X + 1 (X = Ar, CO, N-2). The reactions show an unusually small pre-exponential factor, probably due to the loose binding of X inside the cage.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据