期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 131, 期 42, 页码 15122-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja9072035
关键词
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资金
- Department of Atomic Energy (DAE), Government of India
- CSIR [NWP-0023]
- University Grants Commission (UGC)
The reversible shift of emission in fluorescent molecular gelators has been explored for the preparation of a composite polymer film useful for erasable thermal imaging and secret documentation. A gelation-assisted photopolymerization of styrene allowed the entrapment of the fluorescent gelator molecules within a polystyrene matrix with a weak green fluorescence, which upon heating above the T. of the polymer resulted in high-contrast fluorescence images due to the strong blue fluorescence of the individual molecules. The blue emission from the disassembled oligo(p-phenylenevinylene) molecules (OPVs) could be reversed to the green emission of the self-assembled OPVs by exposing the polymer film to chloroform vapors. The thermally written images are visible only under UV light and cannot be photocopied. A solvent-vapor-control led recreation of the self-assembly of a fluorescent organogelator within a polymer matrix and its application in erasable secret documentation has not been reported previously.
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