期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 131, 期 5, 页码 1674-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja809181m
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资金
- National Science Foundation
- National Institutes of Health [GM33049]
- Stanford University for a graduate fellowship
- Bing Fellowship
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0846427] Funding Source: National Science Foundation
Magnesium-catalyzed enantioselective aldol between ethyl diazoacetate and aromatic, aliphatic, and alpha,beta-unsaturated aldehydes affords alpha-diazo-beta-hydroxy-esters in high enantioselectivities. Aldol adducts resulting from this asymmetric transformation are versatile intermediates toward the synthesis of several ester containing chiral building blocks.
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