期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 131, 期 40, 页码 14192-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja906566r
关键词
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资金
- MEXT [20685005, 21108507]
- Shin-etsu Chemical Co., Ltd.
- Tosoh Finechem Co., Ltd.
- Central Glass Co., Ltd.
- Grants-in-Aid for Scientific Research [21350025, 21108507, 20685005] Funding Source: KAKEN
An intramolecular sila-Friedel-Crafts reaction was developed and applied to the synthesis of dibenzosilole derivatives. This reaction proceeds under mild conditions to afford the target in relatively high yield, indicating its availabilty as a versatile synthetic method. The synthesis of trisilasumanene, a silicon analogue of sumanene, was achieved using the present reaction.
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