期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 131, 期 33, 页码 11701-11706出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja903939k
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资金
- NIH/NIGMS [GM076153]
A Bronsted base activation mode for oxidative, Pd(II)/sulfoxide-catalyzed, intermolecular C-H allylic amination is reported. N,N-diisopropylethylamine was found to promote amination of unactivated terminal olefins, forming the corresponding linear allylic amine products with high levels of stereo-, regio-, and chemoselectivity. The predictable and high selectivity of this C-H oxidation method enables late-stage incorporation of nitrogen into advanced synthetic intermediates and natural products.
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