期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 131, 期 19, 页码 6695-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja902045q
关键词
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资金
- NIH [GM-057052]
- Pao Yu-Kong and Pao Zhao-Long Scholarship
- NSF [CHE-0616505]
We present a general strategy for the synthesis of stable, multifunctional cuboctahedral complexes in which coordination-driven self-assembly allows for precise control over positioning of either ferrocene or crown ether functionalities. The appropriate stoichiometric combination of functionalized 120 degrees diplatinum acceptor units with tritopic donor units afforded supramolecular cuboctahedra with covalently linked functional groups. The compounds are characterized by multinuclear NMR spectroscopy, electrospray ionization mass spectrometry, and electrochemistry.
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