期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 131, 期 43, 页码 15624-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja906033g
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资金
- NSERC (Canada)
- Canada Foundation for Innovation
- Canada Research Chair Program
- Universite de Montreal
The first asymmetric cyclopropanation of allylic alcohols using gem-dizinc carbenoids, which allows the synthesis of 1, 2,3-substituted cyclopropane derivatives in high yields and excellent enantio- and diastereoselectivities, is reported. The initially formed cyclopropylzinc undergoes an in situ B/Zn exchange with the stoichiometric chiral ligand to generate a cyclopropyl borinate that can be directly engaged in a Suzuki-Miyaura cross-coupling reaction.
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