期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 130, 期 33, 页码 10848-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja802533u
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资金
- NSERC
- Research Corporation
- Sloan Foundation
- ACS (PRF AC)
- Merck Frosst
- Merck Inc
- CFI
- ORF
The concerted metalation-deprotonation mechanism predicts relative reactivity and regioselectivity for a diverse set of arenes spanning the entire spectrum of known palladium-catalyzed direct arylation coupling partners. An analysis following an active strain model provides a more complete portrayal of the important arene/catalyst parameters leading to a successful coupling. The breadth of arenes whose reactivity can be predicted by the CMD mechanism indicates that it may be far more widespread than previously imagined.
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