期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 130, 期 29, 页码 9196-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja802123p
关键词
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Carbon-heteroatom bond formation from copper(III) is commonly invoked as a key step in catalytic reactions, including the century-old Ullmann reactions. Well-defined examples of such reactions have never been observed. Here, we demonstrate that a well-defined Cu(III)-aryl species reacts with a variety nitrogen nucleophiles to undergo facile carbon-nitrogen bond formation.
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