期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 130, 期 51, 页码 17208-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja806791c
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资金
- German Research Association (DFG) [SSP 1179]
The desolvating droplets of EESI were used as microreactor for the mass spectrometric study of short-lived transients of reactions in condensed liquid phase in the millisecond time region, The electron-transfer-catalyzed dimerization of trans-anethole was investigated and the intermediates in the radical cation chain reaction were isolated and characterized by MS-MS. The distonic tetramethylene radical cation 3(o)(.+) was detected as intermediate, and its cyclization to give the cyclobutane radical cation 3(c)(.+) was observed giving strong evidence that the reaction takes place stepwise.
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