期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 130, 期 44, 页码 14368-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja804885k
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资金
- MEXT of Japan
- Global COE Program for Chemistry Innovation
A discrete 2-nm-sized self-assembled organic capsule was formed from the union of six hexagram-shaped amphiphile molecules in aqueous methanol due to the hydrophobic effect, van der Waals forces, and CH-Pi interactions between the chemical components. A couple of hexa-substituted benzene molecules were encapsulated inside the capsule in both solution and the solid state, as was evidenced by H-1 NMR spectroscopy and single-crystal X-ray analysis.
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