期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 130, 期 35, 页码 11650-11661出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja803783c
关键词
-
资金
- U.S. Departrnent of Energy [DE-FG36-05GO15001, DE-FG02-08ER15935]
- BASF (Ludwigshafen, Germany)
- Korea Research Foundation [KRF 2003-070-CO0029]
Metal-organic polyhedra and frameworks (MOPS and MOFs) were prepared by linking square units M-2(CO2)(4) (M = Cu and Zn) with a variety of organic linkers designed to control the dimensionality (periodicity) and topology of the resulting structures. We describe the preparation, characterization, and crystal structures of 5 new MOPS and 11 new MOFs (termed MOP-14, -15, -17, -23, -24 and MOF-114, -115, -116, -117, -118, -119, -222, -601, -602, -603, -604) and show how their structures are related to the shape and functionality of the building blocks. The gas uptake behaviors of MOP-23 and MOF-601 to -603 are also presented as evidence that these structures have permanent porosity and rigid architectures.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据