期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 130, 期 21, 页码 6686-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja801137k
关键词
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资金
- NIGMS NIH HHS [GM-F32-75685, R01 GM058160-11, F32 GM075685-01, R01 GM058160, R37 GM046059, GM-058160] Funding Source: Medline
A new class of one-component Pd precatalysts bearing biarylphosphine ligands is described. These precatalysts are air- and thermally stable, are easily activated under normal reaction conditions at or below room temperature and ensure the formation of the highly active monoligated Pd(0) complex necessary for oxidative addition. The use of these precatalysts as a convenient source of LPd(0) in C-N cross-coupling reactions is explored. The reactivity that is demonstrated in this study is unprecedented in palladium chemistry.
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