期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 130, 期 38, 页码 12606-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja804753n
关键词
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资金
- Ministry of Science and Technology of Korea [R0A-2006-000-10269-0, R11-2005-008-000000]
- Korea Research Foundation [KFR-2004-005-C00093]
- Natural Sciences and Engineering Research Council of Canada
- National Research Foundation of Korea [2004-005-C00093, R0A-2006-000-10269-0] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
A dinuclear copper complex that binds tightly and selectively to oxalate over other dicarboxylates like malonate, succinate, and glutarate has been developed. This receptor can be used for fluorescent detection of oxalate in water at physicological pH by chemosensing ensemble approach. Crystal structure of oxalate bound to the receptor together with molecular mechanics and DFT computations provide insights into the tight and selective binding of the anion by the receptor.
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