期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 130, 期 10, 页码 2926-2927出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja710731a
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We report the first room-temperature direct C-2 arylation of indoles with iodoarenes by using a highly electrophilic palladium catalyst generated in situ from Pd(OAc)(2) and a silver carboxylate. These mild conditions permit a broad set of functionalities both in the indole and in the aryl iodide units such as free alcohols, phenols, aldehydes, bromides, or nitriles, thus allowing the synthesis of a variety of novel compounds in excellent yields.
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