期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 130, 期 1, 页码 66-73出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja073975t
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We succeeded in establishing for the first time a conclusive spectroscopic signature for reduced single-wall carbon nanotubes (SWNT), which evolves from electron donor-acceptor interactions between SWNT and electron-donating pi-extended tetrathiafulvalene (exTTF). in particular, pi-pi interactions were employed to anchor the electron donor to the surface of SWNT. New conduction band electrons, injected from photoexcited exTTF, shift the transitions that are associated with the van Hove singularities to lower energies.
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