期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 130, 期 37, 页码 12228-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja8043695
关键词
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资金
- NIH [R01GM082961]
- Eli Lilly, Michigan State University
- University Distinguished Fellowship
- Dow Chemical Company Foundation
The syntheses of haterumalides NA and NC were accomplished via the macrocyclization of a chlorovinylidene chromium carbenoid onto a pendant aldehyde to generate the C8-C9 bond with the desired stereoisomer as the major product. Utilizing the latter chemistry enables access to both C9 hydroxylated (haterumalides NC and ND) and C9 deoxygenated forms (haterumalides NA, NB, and NE; via deoxygenation of the C9-hydroxyl).
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