期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 130, 期 48, 页码 16158-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja806897h
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资金
- EEWS program of KAIST
- KRF [KRF-2006-312-C00587]
A new strategy for the synthesis of condensed hetero- or carbocycles such as pyrroloindoles or fluorenes has been developed that involves the Pd-catalyzed cyclization of readily available N-(2-halobenzyl)pyrroles or their phenyl derivatives. The reaction is proposed to proceed via oxidative addition of benzylic halides to Pd(0) followed by base-assisted C-H bond activation. A broad range of condensed cyclic products could be obtained in good to excellent yields under mild conditions.
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