期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 130, 期 18, 页码 5858-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja800818b
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An iron-catalyzed C-C bond formation reaction of a nitrogencontaining aromatic compound with an arylzinc reagent takes place at 0 degrees C in a good to quantitative yield. The reaction involves a C-H bond activation directed by a neighboring nitrogen atom. The important additives in this reaction are 1,10-phenanthroline, tetramethylethylenediamine, and 1,2-dichloro2-methylpropane, in the absence of which a very low product yield was observed.
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